[Simpraga2011a] "Comparing monoterpenoid emissions and net photosynthesis of beech ( Fagus sylvatica L.) in controlled and natural conditions",
, vol. 45, no. 17: Elsevier, pp. 2922–2928, 2011.
<p>Although biogenic volatile organic compounds (BVOCs) only represent a very limited fraction of the plant’s carbon (C) budget, they play an important role in atmospheric chemistry for example as a precursor of tropospheric ozone. We performed a study comparing BVOC emissions of European beech (Fagus sylvatica L.) in controlled and natural environmental conditions. A young and adult beech tree was exposed to short-term temperature variations in growth room conditions and in an experimental forest, respectively. This study attempts to clarify how short-term temperature variations between days influenced the ratio between monoterpenoid (MT) emissions and net photosynthesis (Pn). Within a temperature range of 17–27 °C and 13–23 °C, the MT/Pn carbon ratio increased 10–30 fold for the growth room and forest, respectively. An exponential increasing trend between MT/Pn C ratio and air temperature was observed in both conditions. Beech trees re-emitted a low fraction of the assimilated C back into the atmosphere as MT: 0.01–0.12% and 0.01–0.30% with a temperature rise from 17 to 27 °C and 13–23 °C in growth room and forest conditions, respectively. However, the data showed that the MT/Pn C ratio of young and adult beech trees responded significantly to changes in temperature.</p>
[Joo2011] "Constitutive versus heat and biotic stress induced BVOC emissions in Pseudotsuga menziesii",
, vol. 45, no. 22: Elsevier, pp. 3655–3662, 2011.
Induced volatiles have been a focus of recent research, as not much is known of their emission behavior or atmospheric contribution. BVOC emissions were measured from Pseudotsuga menziesii saplings under natural environmental conditions, using a dynamic branch enclosure system and GC–MS for their analysis. We determined temperature and light dependency of the individual compounds, studied seasonality of the emissions and discuss the effect of heat stress in comparison with two specific biotic stresses that occurred naturally on the trees. A standardized emission rate of 6.8 μg g(dw)−1 h−1 for monoterpenes under stressed conditions was almost a magnitude higher than that obtained for healthy trees (0.8 ± 0.2 μg g(dw)−1 h−1), with higher beta factors characterizing the stressed trees. The response of the emissions to light intensity was different for the individual compounds, suggesting a distinct minimum light intensity to reach saturation. Heat stress changed the relative contribution of specific volatiles, with larger extent of increase of sesquiterpenes, methyl salicylate and linalool emissions compared to monoterpenes. Biotic stress kept low the emissions of sesquiterpenes, (E)-4,8-dimethyl-1,3,7-nonatriene and methylbutenol isomers, and increased the level of methyl salicylate and monoterpenes. The ratio of β-pinene/α-pinene was also found to be significantly enhanced from 1.3 to 2.4 and 3.2 for non-stressed, heat stressed and combined biotic and heat stressed, respectively.
[Cappellin2011a] "On data analysis in PTR-TOF-MS: From raw spectra to data mining",
Sensors and actuators B: Chemical
, vol. 155, no. 1: Elsevier, pp. 183–190, 2011.
Recently the coupling of proton transfer reaction ionization with a time-of-flight mass analyser (PTR-TOF-MS) has been proposed to realise a volatile organic compound (VOC) detector that overcomes the limitations in terms of time and mass resolution of the previous instrument based on a quadrupole mass analysers (PTR-Quad-MS). This opens new horizons for research and allows for new applications in fields where the rapid and sensitive monitoring and quantification of volatile organic compounds (VOCs) is crucial as, for instance, environmental sciences, food sciences and medicine. In particular, if coupled with appropriate data mining methods, it can provide a fast MS-nose system with rich analytical information. The main, perhaps even the only, drawback of this new technique in comparison to its precursor is related to the increased size and complexity of the data sets obtained. It appears that this is the main limitation to its full use and widespread application. Here we present and discuss a complete computer-based strategy for the data analysis of PTR-TOF-MS data from basic mass spectra handling, to the application of up-to date data mining methods. As a case study we apply the whole procedure to the classification of apple cultivars and clones, which was based on the distinctive profiles of volatile organic compound emissions.
[Bamberger2011] "Deposition fluxes of terpenes over grassland",
Journal of Geophysical Research: Atmospheres (1984–2012)
, vol. 116, no. D14: Wiley Online Library, 2011.
Eddy covariance flux measurements were carried out for two subsequent vegetation periods above a temperate mountain grassland in an alpine valley using a proton-transfer-reaction-mass spectrometer (PTR-MS) and a PTR time-of-flight-mass spectrometer (PTR-TOF). In 2008 and during the first half of the vegetation period 2009 the volume mixing ratios (VMRs) for the sum of monoterpenes (MTs) were typically well below 1 ppbv and neither MT emission nor deposition was observed. After a hailstorm in July 2009 an order of magnitude higher amount of terpenes was transported to the site from nearby coniferous forests causing elevated VMRs. As a consequence, deposition fluxes of terpenes to the grassland, which continued over a time period of several weeks without significant reemission, were observed. For days without precipitation the deposition occurred at velocities close to the aerodynamic limit. In addition to monoterpene uptake, deposition fluxes of the sum of sesquiterpenes (SQTs) and the sum of oxygenated terpenes (OTs) were detected. Considering an entire growing season for the grassland (i.e., 1 April to 1 November 2009), the cumulative carbon deposition of monoterpenes reached 276 mg C m−2. This is comparable to the net carbon emission of methanol (329 mg C m−2), which is the dominant nonmethane volatile organic compound (VOC) emitted from this site, during the same time period. It is suggested that deposition of monoterpenes to terrestrial ecosystems could play a more significant role in the reactive carbon budget than previously assumed.
[Jordan2011] "Detection and Identification of Illicit and Hazardous Substances with Proton-Transfer-Reaction Mass Spectrometry (PTR-MS)",
: IONICON Analytik, 2011.
[Sulzer2011] "Detection of explosives Detection of explosives with Proton Transfer Reaction Transfer Reaction-Mass Spectrometry Mass Spectrometry",
[Brilli2011] "Detection of plant volatiles after leaf wounding and darkening by proton transfer reaction "time-of-flight" mass spectrometry (PTR-TOF).",
, vol. 6, no. 5: Ionicon Analytik G.m.b.H., Innsbruck, Austria., pp. e20419, 2011.
Proton transfer reaction-time of flight (PTR-TOF) mass spectrometry was used to improve detection of biogenic volatiles organic compounds (BVOCs) induced by leaf wounding and darkening. PTR-TOF measurements unambiguously captured the kinetic of the large emissions of green leaf volatiles (GLVs) and acetaldehyde after wounding and darkening. GLVs emission correlated with the extent of wounding, thus confirming to be an excellent indicator of mechanical damage. Transient emissions of methanol, C5 compounds and isoprene from plant species that do not emit isoprene constitutively were also detected after wounding. In the strong isoprene-emitter Populus alba, light-dependent isoprene emission was sustained and even enhanced for hours after photosynthesis inhibition due to leaf cutting. Thus isoprene emission can uncouple from photosynthesis and may occur even after cutting leaves or branches, e.g., by agricultural practices or because of abiotic and biotic stresses. This observation may have important implications for assessments of isoprene sources and budget in the atmosphere, and consequences for tropospheric chemistry.
[Han2011] "Development of a novel methodology for indoor emission source identification",
, vol. 45, no. 18: Pergamon, pp. 3034–3045, 2011.
The objective of this study was to develop and evaluate a methodology to identify individual sources of emissions based on the measurements of mixed air samples and the emission signatures of individual materials previously determined by Proton Transfer Reaction-Mass Spectrometry (PTR-MS), an on-line analytical device. The methodology based on signal processing principles was developed by employing the method of multiple regression least squares (MRLS) and a normalization technique. Samples of nine typical building materials were tested individually and in combination, including carpet, ceiling material, gypsum board, linoleum, two paints, polyolefine, PVC and wood. Volatile Organic Compound (VOC) emissions from each material were measured in a 50-liter small-scale chamber. Chamber air was sampled by PTR-MS to establish a database of emission signatures unique to each individual material. The same task was performed to measure combined emissions from material mixtures for the application and validation of the developed signal separation method. Results showed that the proposed method could identify the individual sources under laboratory conditions with two, three, five and seven materials present. Further experiments and investigation are needed for cases where the relative emission rates among different compounds may change over a long-term period.
 "Direct ecosystem fluxes of volatile organic compounds from oil palms in South-East Asia",
Atmospheric Chemistry and Physics
, vol. 11, pp. 8995–9017, 2011.
<p>This paper reports the first direct eddy covariance fluxes of reactive biogenic volatile organic compounds (BVOCs) from oil palms to the atmosphere using proton-transfer-reaction mass spectrometry (PTR-MS), measured at a plantation in Malaysian Borneo. At midday, net isoprene flux constituted the largest fraction (84 %) of all emitted BVOCs measured, at up to 30 mg m−2 h−1 over 12 days. By contrast, the sum of its oxidation products methyl vinyl ketone (MVK) and methacrolein (MACR) exhibited clear deposition of 1 mg m−2 h−1, with a small average canopy resistance of 230 s m−1. Approximately 15 % of the resolved BVOC flux from oil palm trees could be attributed to floral emissions, which are thought to be the largest reported biogenic source of estragole and possibly also toluene. Although on average the midday volume mixing ratio of estragole exceeded that of toluene by almost a factor of two, the corresponding fluxes of these two compounds were nearly the same, amounting to 0.81 and 0.76 mg m−2 h−1, respectively. By fitting the canopy temperature and PAR response of the MEGAN emissions algorithm for isoprene and other emitted BVOCs a basal emission rate of isoprene of 7.8 mg m−2 h−1 was derived. We parameterise fluxes of depositing compounds using a resistance approach using direct canopy measurements of deposition. Consistent with Karl et al. (2010), we also propose that it is important to include deposition in flux models, especially for secondary oxidation products, in order to improve flux predictions.</p>
[Biasioli2011] "Direct-injection mass spectrometry adds the time dimension to (B) VOC analysis",
TrAC Trends in Analytical Chemistry
, vol. 30, no. 7: Elsevier, pp. 1003–1017, 2011.
In the past decade, we have witnessed rapid development of direct-injection mass spectrometric (DIMS) technologies that combine ever-improving mass and time resolution with high sensitivity and robustness. Here, we review some of the most significant DIMS technologies, which have been applied to rapid monitoring and quantification of volatile organic compounds (VOCs) and biogenic VOCS (BVOCs). They include MS-e-noses, atmospheric-pressure chemical ionization (APCI), proton-transfer-reaction mass spectrometry (PTR-MS), and selected ion-flow-tube mass spectrometry (SIFT-MS). DIMS-based MS-e-noses provide the possibility to screen large sample sets and may yield rich analytical information. APCI is a widespread ionization method and pioneered DIMS in environmental and flavor-release applications. SIFT-MS and PTR-MS allow better control of precursor-ion generation and hence of the ionization process. SIFT-MS puts the focus on control of the ionization process, while PTR-MS does so on sensitivity. Most (B)VOCs of interest can be efficiently detected and often identified by DIMS, thanks also to the possibility of switching between different precursor ions and the recent realization of time-of-flight-based equipments. Finally, we give selected examples of applications for each of the key technologies, including research in food-quality control (MS-e-nose), flavor release (APCI), environmental sciences (PTR-MS) and health sciences (SIFT-MS).
[Kamysek2011] "Drug detection in breath: effects of pulmonary blood flow and cardiac output on propofol exhalation.",
Anal Bioanal Chem
, vol. 401, no. 7: Department of Anesthesiology and Intensive Care, University of Rostock, Schillingallee 35, 18057 Rostock, Germany., pp. 2093–2102, Oct, 2011.
Breath analysis could offer a non-invasive means of intravenous drug monitoring if robust correlations between drug concentrations in breath and blood can be established. In this study, propofol blood and breath concentrations were determined in an animal model under varying physiological conditions. Propofol concentrations in breath were determined by means of two independently calibrated analytical methods: continuous, real-time proton transfer reaction mass spectrometry (PTR-MS) and discontinuous solid-phase micro-extraction coupled with gas chromatography mass spectrometry (SPME-GC-MS). Blood concentrations were determined by means of SPME-GC-MS. Effects of changes in pulmonary blood flow resulting in a decreased cardiac output (CO) and effects of dobutamine administration resulting in an increased CO on propofol breath concentrations and on the correlation between propofol blood and breath concentrations were investigated in seven acutely instrumented pigs. Discontinuous propofol determination in breath by means of alveolar sampling and SPME-GC-MS showed good agreement (R(2)=0.959) with continuous alveolar real-time measurement by means of PTR-MS. In all investigated animals, increasing cardiac output led to a deterioration of the relationship between breath and blood propofol concentrations (R(2)=0.783 for gas chromatography-mass spectrometry and R(2)=0.795 for PTR-MS). Decreasing pulmonary blood flow and cardiac output through banding of the pulmonary artery did not significantly affect the relationship between propofol breath and blood concentrations (R(2)>0.90). Estimation of propofol blood concentrations from exhaled alveolar concentrations seems possible by means of different analytical methods even when cardiac output is decreased. Increases in cardiac output preclude prediction of blood propofol concentration from exhaled concentrations.
[Deleris2011a] "The dynamics of aroma release during consumption of candies of different structures, and relationship with temporal perception",
, vol. 127, no. 4: Elsevier, pp. 1615–1624, 2011.
We investigated the role of both candy texture and eating technique (melting or chewing) on the dynamics of aroma release. One novelty of this type of analysis was the simultaneous application of instrumental and sensory analysis. Four candy textures were established based on their storage modulus at 1 Hz by varying the gelatine content between 0 and 15% w/w. The invivo release of three aroma compounds was monitored using Proton Transfer Reaction Mass Spectrometry and with a trained panel of testers. The gelatine content had no significant effect on the headspace/product partition and diffusion properties of the aroma compounds. The highest invivo release for all aroma compounds was obtained with the 2% gelatine sample. Our findings indicated that aroma release was determined by interaction between the product properties and oral behaviour. Relations between the dynamics of release and perception (method of Temporal Dominance of Sensations) have been established on temporal parameters.
[Ruuskanen2011] "Eddy covariance VOC emission and deposition fluxes above grassland using PTR-TOF",
Atmos. Chem. Phys
, vol. 11, pp. 611–625, 2011.
Eddy covariance (EC) is the preferable technique for flux measurements since it is the only direct flux determination method. It requires a continuum of high time resolution measurements (e.g. 5–20 Hz). For volatile organic compounds (VOC) soft ionization via proton transfer reaction has proven to be a quantitative method for real time mass spectrometry; here we use a proton transfer reaction time of flight mass spectrometer (PTR-TOF) for 10 Hz EC measurements of full mass spectra up to m/z 315. The mass resolution of the PTR-TOF enabled the identification of chemical formulas and separation of oxygenated and hydrocarbon species exhibiting the same nominal mass. We determined 481 ion mass peaks from ambient air concentration above a managed, temperate mountain grassland in Neustift, Stubai Valley, Austria. During harvesting we found significant fluxes of 18 compounds distributed over 43 ions, including protonated parent compounds, as well as their isotopes and fragments and VOC-H+ – water clusters. The dominant BVOC fluxes were methanol, acetaldehyde, ethanol, hexenal and other C6 leaf wound compounds, acetone, acetic acid, monoterpenes and sequiterpenes.
 "Effect of Cigarette Menthol Content on Mainstream Smoke Emissions",
Chemical Research in Toxicology
, vol. 24, pp. 1744-1753, 2011.
<p>The 2009 Family Smoking Prevention and Tobacco Control Act empowered the U.S. Food and Drug Administration to study “the impact of the use of menthol in cigarettes on the public health, including such use among children, African Americans, Hispanics and other racial and ethnic minorities,” and develop recommendations. Current scientific evidence comparing human exposures between menthol and nonmenthol smokers shows mixed results. This is largely because of the many differences between commercial menthol and nonmenthol cigarettes other than their menthol content. We conducted an innovative study using two types of test cigarettes: a commercial nonmenthol brand that we mentholated at four different levels, and Camel Crush, a commercial cigarette containing a small capsule in the filter that releases menthol solution into the filter when crushed. Cigarettes were machine-smoked at each of the menthol levels investigated, and the total particulate matter (TPM) was collected on a quartz fiber filter pad and analyzed by gas chromatography/mass spectrometry for menthol, nicotine, tobacco-specific nitrosamines (TSNAs), polycyclic aromatic hydrocarbons (PAHs), cotinine, and quinoline. The mainstream smoke was also monitored continuously in real time on a puff-by-puff basis for seven gas-phase constituents (acetaldehyde, acetonitrile, acrylonitrile, benzene, 1,3-butadiene, isoprene, and 2,5-dimethylfuran), using a proton transfer reaction-mass spectrometer. Average yields (in micrograms/cigarette) for the analytes were determined. Menthol in the TPM samples increased linearly with applied menthol concentration, but the amounts of nicotine along with the target TSNAs, PAHs, cotinine, and quinoline in the cigarettes remained essentially unchanged. Similarly, yields of the targeted volatile organic compounds (VOCs) in whole smoke from the mentholated nonmenthol cigarettes that were measured in real-time were largely unaffected by their menthol levels. In the Camel Crush cigarettes, however, the VOC yields appeared to increase in the presence of menthol, especially in the gas phase. Although we succeeded in characterizing key mainstream smoke constituents in cigarettes that differ only in menthol content, further study is needed to definitively answer whether menthol affects exposure to selected cigarette constituents and thereby influences harm.</p>
[Liu2011] "The effect of slurry treatment including ozonation on odorant reduction measured by in-situ PTR-MS",
, vol. 45, no. 23: Elsevier, pp. 3786–3793, 2011.
The emission of odorous compounds from intensive pig production facilities is a nuisance for neighbors. Slurry ozonation for odor abatement has previously been demonstrated in laboratory scale. In this study, the effect of slurry ozonation (combined with solid–liquid pre-separation and acidification) on emissions of odorous compounds was tested in an experimental full-scale growing pig facility using Proton-Transfer-Reaction Mass Spectrometry (PTR-MS) for online analysis of odorants. The measurements were performed to gain a better understanding of the effects of ozone treatment on emissions odorous compounds and to identify potential options for optimization of ozone treatment. The compounds monitored included volatile sulfur compounds, amine, carboxylic acids, ketones, phenols and indoles. Measurements were performed during nearly a one-month period in summertime. The compounds with the highest concentrations observed in the ventilation exhaust duct were acetic acid, hydrogen sulfide, propanoic acid and butanoic acid. The compounds with the highest removal efficiencies were hydrogen sulfide, 3-methyl-indole, phenol and acetic acid. Based on odor threshold values, methanethiol, butanoic acid, 4-methylphenol, hydrogen sulfide and C5 carboxylic acids are estimated to contribute significantly to the odor nuisance. Emissions of odorous compounds were observed to be strongly correlated with temperature with the exception of hydrogen sulfide. Emission peaks of sulfur compounds were seen during slurry handling activities. Discharging of the slurry pit led to reduced hydrogen sulfide emissions, but emissions of most other odorants were not affected. The results indicate that emissions of odorants other than hydrogen sulfide mainly originate from sources other than the treated slurry, which limits the potential for further optimization. The PTR-MS measurements are demonstrated to provide a quantitative, accurate and detailed evaluation of ozone treatment for emission reduction.
[Saha2011] "Effects of airflow on odorants' emissions in a model pig house - A laboratory study using Proton-Transfer-Reaction Mass Spectrometry (PTR-MS).",
Sci Total Environ
, vol. 410-411: Department of Engineering, Aarhus University, Blichers AllÃ© 20, 8830 Tjele, Denmark. firstname.lastname@example.org, pp. 161–171, Dec, 2011.
Identification of different factors that affect emissions of gasses, including volatile organic compounds (VOCs) is necessary to develop emission abatement technology. The objectives of this research were to quantify and study temporal variation of gas emissions from a model pig house under varying ventilation rates. The used model was a 1:12.5 scale of a section of a commercial finishing pig house. The VOC concentrations at inlet, outlet, and slurry pit of the model space were measured using Proton-Transfer-Reaction Mass Spectrometry (PTR-MS). PTR-MS can measure the temporal variations of odor compounds' emission from the slurry pit in real time. The emissions of H(2)S and 14 VOCs were lower compared to real pig buildings except for ammonia, which indicated possible other sources of those compounds than the slurry in the slurry pit. The ventilation rate affected significantly on ammonia and trimethylamine emission (p<0.05). The hydrogen sulfide (H(2)S) emission was independent of the ventilation rate. VFAs' emission dependency on ventilation rate increased with the increase of carbon chain. Phenols, indoles and ketones showed the positive correlation with ventilation rate to some extent. Generally, compounds with high solubility (low Henry's constant) showed stronger correlation with ventilation rates than the compounds with high Henry's constant.
 "Effects of Mentholation on Cigarette Smoke Emissions",
Conference of the Society for Research on Nicotine and Tobacco (SRNT)
, Toronto, Canada, Conference of the Society for Research on Nicotine and Tobacco (SRNT), Feb., 2011.
[Singh2011] "An endophytic Phomopsis sp. possessing bioactivity and fuel potential with its volatile organic compounds",
, vol. 61, no. 4: Springer, pp. 729–739, 2011.
An unusual Phomopsis sp. was isolated as endophyte of Odontoglossum sp. (Orchidaceae), associated with a cloud forest in Northern Ecuador. This fungus produces a unique mixture of volatile organic compounds (VOCs) including sabinene (a monoterpene with a peppery odor) only previously known from higher plants. In addition, some of the other more abundant VOCs recorded by GC/MS in this organism were 1-butanol, 3-methyl; benzeneethanol; 1-propanol, 2-methyl and 2-propanone. The gases of Phomopsis sp. possess antifungal properties and an artificial mixture of the VOCs mimicked the antibiotic effects of this organism with the greatest bioactivity against a wide range of plant pathogenic test fungi including: Pythium, Phytophthora, Sclerotinia, Rhizoctonia, Fusarium, Botrytis, Verticillium, and Colletotrichum. The IC50 values for the artificial gas mixture of Phomopsis sp. varied between 8 and 25.65 μl/mL. Proton transfer reaction-mass spectrometry monitored the concentration of VOCs emitted by Phomopsis sp. and yielded a total VOC concentration of ca. 18 ppmv in the head space at the seventh day of incubation at 23°C on PDA. As with many VOC-producing endophytes, this Phomopsis sp. did survive and grow in the presence of the inhibitory gases of Muscodor albus. A discussion is presented on the possible involvement of VOC production by the fungus and its role in the biology/ecology of the fungus/plant/environmental relationship.
[Fischer2011] "Evaporating Liquid Samples for Analysis with PTR-MS",
5th International PTR-MS Conference on Proton Transfer Reaction Mass Spectrometry and Its Applications
, pp. 211–212, 2011.
We present a method for measuring liquid samples with the PTR-MS by using a spray to convert the liquid into the gas phase. Advantages over headspace measurements concerning compounds with high Henry's law constants could be demonstrated.
[Cappellin2011] "Extending the dynamic range of proton transfer reaction time-of-flight mass spectrometers by a novel dead time correction.",
Rapid Commun Mass Spectrom
, vol. 25, no. 1: IASMA Research and Innovation Centre, Fondazione Edmund Mach, Food Quality and Nutrition Area, Via E. Mach 1, 38010 S. Michele a/A, Italy., pp. 179–183, Jan, 2011.
Proton transfer reaction time-of-flight mass spectrometry (PTR-TOF-MS) allows for very fast simultaneous monitoring of volatile organic compounds (VOCs) in complex environments. In several applications, food science and food technology in particular, peaks with very different intensities are present in a single spectrum. For VOCs, the concentrations range from the sub-ppt all the way up to the ppm level. Thus, a large dynamic range is necessary. In particular, high intensity peaks are a problem because for them the linear dependency of the detector signal on VOC concentration is distorted. In this paper we present, test with real data, and discuss a novel method which extends the linearity of PTR-TOF-MS for high intensity peaks far beyond the limit allowed by the usual analytical correction methods such as the so-called Poisson correction. Usually, raw data can be used directly without corrections with an intensity of up to about 0.1 ions/pulse, and the Poisson correction allows the use of peaks with intensities of a few ions/pulse. Our method further extends the linear range by at least one order of magnitude. Although this work originated from the necessity to extend the dynamic range of PTR-TOF-MS instruments in agro-industrial applications, it is by no means limited to this area, and can be implemented wherever dead time corrections are an issue.
[Stavrakou2011] "First space-based derivation of the global atmospheric methanol emission fluxes",
Atmospheric chemistry and physics
, vol. 11, no. 10: Copernicus GmbH, pp. 4873–4898, 2011.
This study provides improved methanol emission estimates on the global scale, in particular for the largest methanol source, the terrestrial biosphere, and for biomass burning. To this purpose, one complete year of spaceborne measurements of tropospheric methanol columns retrieved for the first time by the thermal infrared sensor IASI aboard the MetOp satellite are compared with distributions calculated by the IMAGESv2 global chemistry-transport model. Two model simulations are performed using a priori biogenic methanol emissions either from the new MEGANv2.1 emission model, which is fully described in this work and is based on net ecosystem flux measurements, or from a previous parameterization based on net primary production by Jacob et al. (2005). A significantly better model performance in terms of both amplitude and seasonality is achieved through the use of MEGANv2.1 in most world regions, with respect to IASI data, and to surface- and air-based methanol measurements, even though important discrepancies over several regions are still present. As a second step of this study, we combine the MEGANv2.1 and the IASI column abundances over continents in an inverse modelling scheme based on the adjoint of the IMAGESv2 model to generate an improved global methanol emission source. The global optimized source totals 187 Tg yr−1 with a contribution of 100 Tg yr−1 from plants, only slightly lower than the a priori MEGANv2.1 value of 105 Tg yr−1. Large decreases with respect to the MEGANv2.1 biogenic source are inferred over Amazonia (up to 55 %) and Indonesia (up to 58 %), whereas more moderate reductions are recorded in the Eastern US (20–25 %) and Central Africa (25–35 %). On the other hand, the biogenic source is found to strongly increase in the arid and semi-arid regions of Central Asia (up to a factor of 5) and Western US (factor of 2), probably due to a source of methanol specific to these ecosystems which is unaccounted for in the MEGANv2.1 inventory. The most significant error reductions achieved by the optimization concern the derived biogenic emissions over the Amazon and over the Former Soviet Union. The robustness of the derived fluxes to changes in convective updraft fluxes, in methanol removal processes, and in the choice of the biogenic a priori inventory is assessed through sensitivity inversions. Detailed comparisons of the model with a number of aircraft and surface observations of methanol, as well as new methanol measurements in Europe and in the Reunion Island show that the satellite-derived methanol emissions improve significantly the agreement with the independent data, giving thus credence to the IASI dataset.
 "Flux Measurements of Biogenic Precursors to Ozone and Particulate Matter in the Central Valley",
Report for the California Air Resources Board and the California Environmental Protection Agency
, Aug, 2011.
Link: http://nature.berkeley.edu/ahg/pubs/ARB FR 2011 CITRUS Final Report Contract 06-329.pdf
[Beck2011] "The gas-phase ozonolysis of ?-humulene.",
Phys Chem Chem Phys
, vol. 13, no. 23: Max Planck Institute for Chemistry, Atmospheric Chemistry Department, Mainz, Germany. email@example.com, pp. 10970–11001, Jun, 2011.
?-Humulene contains three double bonds (DB), and after ozonolysis of the first DB the first-generation products are still reactive towards O(3) and produce second- and third-generation products. The primary aim of this study consisted of identifying the products of the three generations, focusing on the carboxylic acids, which are known to have a high aerosol formation potential. The experiments were performed in a 570 litre spherical glass reactor at 295 K and 730 Torr. Initial mixing ratios were 260-2090 ppb for O(3) and 250-600 ppb for ?-humulene in synthetic air. Reactants and gas-phase products were measured by in situ FTIR spectroscopy. Particulate products were sampled on Teflon filters, extracted with methanol and analyzed by LC-MS/MS-TOF. Using cyclohexane (10-100 ppm) as an OH-radical scavenger and by monitoring the yield of cyclohexanone by PTR-MS, an OH-yield of (10.5 Â± 0.7)% was determined for the ozonolysis of the first DB, and (12.9 Â± 0.7)% of the first-generation products. The rate constant of the reaction of O(3) with ?-humulene is known as k(0) = 1.17 Â± 10(-14) cm(3) molecule(-1) s(-1) [Y. Shu and R. Atkinson, Int. J. Chem. Kinet., 1994, 26, 1193-1205]. The reaction rate constants of O(3) with the first-generation products and the second-generation products were, respectively, determined as k(1) = (3.6 Â± 0.9) x 10(-16) and k(2) = (3.0 Â± 0.7) x 10(-17) cm(3) molecule(-1) s(-1) by Facsimile-simulation of the observed ozone decay by FTIR. A total of 37 compounds in the aerosol phase and 5 products in the gas phase were tentatively identified: 25 compounds of the first-generation products contained C13-C15 species, 9 compounds of the second-generation products contained C8-C11 species, whereas 8 compounds of the third-generation products contained C4-C6 species. The products of all three generations consisted of a variety of dicarboxylic-, hydroxy-oxocarboxylic- and oxo-carboxylic acids. The formation mechanisms of some of the products are discussed. The residual FTIR spectra indicate the formation of secondary ozonides (SOZ) in the gas phase, which are formed by the intramolecular reaction of the Criegee moiety with the carbonyl endgroup. These SOZ revealed to be stable over several hours and its formation was shown not to be affected by the addition of Criegee-radical scavengers such as HCOOH or H(2)O. This suggests that in the ozonolysis of ?-humulene at atmospheric pressures the POZ will decompose rapidly, and that a large fraction of the formed exited Criegee Intermediate will be stabilized to form stable SOZ, while the formation of OH-radicals via the hydroperoxide channel will be a minor process.
 "Ground-level ozone influenced by circadian control of isoprene emissions",
, vol. 4, pp. 671–674, 2011.
<p>The volatile organic compound isoprene is produced by many plant species, and provides protection against biotic and abiotic stresses1. Globally, isoprene emissions from plants are estimated to far exceed anthropogenic emissions of volatile organic compounds2. Once in the atmosphere, isoprene reacts rapidly with hydroxyl radicals3 to form peroxy radicals, which can react with nitrogen oxides to form ground-level ozone4. Here, we use canopy-scale measurements of isoprene fluxes from two tropical ecosystems in Malaysia—a rainforest and an oil palm plantation—and three models of atmospheric chemistry to explore the effects of isoprene fluxes on ground-level ozone. We show that isoprene emissions in these ecosystems are under circadian control on the canopy scale, particularly in the oil palm plantation. As a result, these ecosystems emit less isoprene than present emissions models predict. Using local-, regional- and global-scale models of atmospheric chemistry and transport, we show that accounting for circadian control of isoprene emissions brings model predictions of ground-level ozone into better agreement with measurements, especially in isoprene-sensitive regions of the world.</p>
[Brunner2011] "Headspace measurements of irradiated in vitro cultured cells using PTR-MS.",
Radiat Environ Biophys
, vol. 50, no. 1: Department of Medical Radiation Physics and Diagnostics, Helmholtz Zentrum Muenchen, German Research Center for Environmental Health, Ingolstaedter Landstrasse 1, 85764, Neuherberg, Germany. firstname.lastname@example.org, pp. 209–217, Mar, 2011.
A pilot study was performed to evaluate a new concept for a radiation biodosimetry method. Proton transfer reaction-mass spectrometry (PTR-MS) was used to find out whether radiation induces changes in the composition of volatile organic compounds (VOCs) in the headspace of in vitro cultured cells. Two different cell lines, retinal pigment epithelium cells hTERT-RPE1 and lung epithelium cells A-549, were irradiated with gamma radiation at doses of 4 Gy and 8 Gy. For measuring the cell-specific effects, the VOC concentrations in the headspace of flasks containing cells plus medium, as well as of flasks containing pure medium were analyzed for changes before and after irradiation. No significant radiation-induced alterations in VOC concentrations in the headspace could be observed after irradiation.